Corrosion Behavior Research Articles

Corrosion and Biofouling Behaviors of Self‐Organized Structures on Steel Surface Fabricated by Femtosecond Laser

Self‐organized ripple and pillar structures are fabricated on steel surface using femtosecond laser. Their wettability is investigated in terms of static contact angle, roughness, and chemical bonds. The pillar structure is treated in low surface energy solution to further improve its hydrophobicity. The corrosion and biofouling behaviors of the structures in sea water are investigated by electrochemical and chlorella immersion experiments, respectively. The results show that the ripple structure is hydrophilic with a static contact angle similar to the original surface, while the pillar structure is highly hydrophobic since it has higher roughness and amount of non polar chemical bonds. The pillar structure is further transferred to superhydrophobic through the low surface energy treatment. The improved hydrophobicity facilitates a better anti‐corrosion and anti‐biofouling behavior, and the superhydrophobic pillar structure exhibits the best performance due to its strongest ability to repel water and chlorella adhesion.

Corrosion behavior of austenitic stainless steel and nickel-based welded joints in underwater wet welding

Marine structures such as ports, bridges, pipelines, vessels, and platforms are an essential part of modern infrastructure, where the use of higher-strength steel provides savings in logistics and construction. However, the repair of higher-strength steels can be challenging, especially underwater. Wet shielded metal arc welding is the most widely used and least expensive method for underwater welding repairs, but is very susceptible to hydrogen-induced cracking. Thus, researchers and welding engineers aim to reduce the amount of hydrogen in the weld material. Recent success has been achieved through the use of austenitic welding consumables, such as austenitic stainless steel and nickel-based electrodes. The use of these consumables drastically reduces the amount of diffusible hydrogen in the weld metal. However, these austenitic materials usually have different corrosion potential as compared to the structural steel the weld beads are applied to. This creates the risk of severe galvanic corrosion. In the presented study, the corrosion behavior of welds created with austenitic stainless steel and nickel-based electrodes were studied. Samples were aged for 1.5 years in the Baltic Sea. Simultaneously, the effectiveness of corrosion protection systems such as coating and Impressed Current Cathodic Protection (ICCP) were evaluated. Localized corrosion occurred in the heat-affected zone when austenitic electrodes were used in the corrosive environment. The localized corrosion depth after 1.5 years in the Baltic Sea and in the salt spray layer was approximately 250 µm and 390 µm, respectively. The ICCP system and the use of a coating were effective in preventing localized corrosion. The low pitting corrosion density of 2.5 × 103 m−2 corresponds to grade A1 according to the standard and was found to be negligible as compared to the localized corrosion in the heat-affect zone.

The Effect of Extrusion Ratio on the Discharge and Corrosion Behavior of Mg-3Al-2.8Y-0.7Mn Alloy

The Effect of Extrusion Ratio on the Discharge and Corrosion Behavior of Mg-3Al-2.8Y-0.7Mn Alloy

Study on Galvanic Corrosion Behavior of AH36 Steel and TC4 Alloy Processed by Plasma Electrolytic Oxidation

Study on Galvanic Corrosion Behavior of AH36 Steel and TC4 Alloy Processed by Plasma Electrolytic Oxidation

Effect of Temperature and Concentration on the Corrosion Behavior of 42CrMoE Low Alloy Steel in Boric Acid Solution

Effect of Temperature and Concentration on the Corrosion Behavior of 42CrMoE Low Alloy Steel in Boric Acid Solution

An investigation of the corrosion behavior of zinc-coated stainless steel orthodontic wires: the effect of physical vapor deposition method

BackgroundReleasing of metal ions might implicate in allergic reaction as a negative subsequent of the corrosion of Stainless Steel (SS304) orthodontic wires. The aim of this study was to evaluate the corrosion resistance of zinc-coated (Zn-coated) SS orthodontic wires.MethodsZinc coating was applied on SS wires by PVD method. Electrochemical impedance spectroscopy (EIS), Potentiodynamic polarization tests and Tafel analysis methods were used to predict the corrosion behavior of Zn-coated and uncoated SS wires in both neutral and acidic environments.ResultsThe values of Ecorr ,icorr and Rct ,which were the electrochemical corrosion characteristics, reported better corrosion behavior of Zn-coated SS wires against uncoated ones in both artificial saliva and fluoride-containing environments. Experimental results of the Tafel plot analyses were consistent with that of electrochemical impedance spectroscopy analyses for both biological solutions.ConclusionApplying Zn coating on bare SS orthodontic wire by PVD method might increase the corrosion resistance of the underlying stainless-steel substrate.

Effect of gasket material on flange face corrosion

Bolted flanged joints play a crucial role in connecting pressure vessels and piping systems. The corrosion of the flange surface is one of the most common causes of leakage failure in bolted flanged joints. This research investigates the effect of three gasket materials on the corrosion behavior of 321 stainless steel flange material using a novel setup specially designed for corrosion quantification of such assemblies. The results show that graphite gaskets cause more corrosion to flange surfaces under the same working conditions compared to graphite gaskets with metal foil inserts and virgin polytetrafluoroethylene (PTFE) gaskets. The mechanism of flange face corrosion is that, for PTFE gaskets, corrosion propagation mainly occurs at the gasket inner diameter and propagates through the depth of the flange while, for graphite gaskets, corrosion occurs on the whole contact surface of the flange and the gasket.

The relationship between austenite stabiliser element and post-weld heat treatment on the corrosion behaviour of the welded duplex stainless steel made by gas tungsten arc welding

The corrosion behaviour and the influence of nickel and post-weld heat treatment (PWHT) on the susceptibility to corrosion in welded duplex stainless steels were investigated. After PWHT, the amount of nickel for the weld region increases resulting in the generation of austenite and consequently, helping to obtain a favourable ferrite-to-austenite ratio. Comparing the experimental outcomes, it is noticed that the pits initiate and propagate in HAZ indicating this area is more susceptible to corrosion resistance compared to the fusion zone. The pitting resistance equivalent number alone is not sufficient reason to study the complex corrosion phenomenon, and the influence of other parameters namely microstructural evolution on the breakdown of passivity by pitting and the existence of intermetallic phases should be determined together.

Processing of Shape Memory Alloys research, applications and opportunities: A Review

Abstract Shape Memory Alloys (SMAs) are metallic materials with unique thermomechanical characteristics that can regain their original shape after deformation. SMAs can be used in various industries such as consumer electronics, automobile parts, aircraft components, and biomedical devices. In this paper, we review the current state of the art of SMA fabrication and their application in the aerospace, healthcare, and aerospace industries. Specifically, we focus on the influence of manganese (Mn) addition on Cu-Al-Ni shape memory alloys' structure, mechanical characteristics, and corrosion behavior, focusing on the incorporation of small and medium-sized enterprises (SMEs) in the analysis of cu-aluminum alloys. This study explores the integration of SME and superelasticity, critical phenomena in SMA behavior, and can be utilized to develop and evaluate SMA-based devices and structures, as well as to understand the mechanism behind SMA actuation and develop improved materials. FEM simulations are crucial for optimizing designs and enhancing performance in sectors like aerospace and healthcare. FEM simulations can also be used to predict the stress and strain of SMA-based devices and structures. This can help to reduce cost, improve efficiency, and reduce the risk of failure. Additionally, FEM simulations can help to identify potential weaknesses in SMA-based designs and suggest modifications or improvements.

Corrosion Behavior of Al2O3-40TiO2 Coating Deposited on 20MnNiMo Steel via Atmospheric Plasma Spraying in Hydrogen Sulfide Seawater Stress Environments

In this study, an Al2O3-40TiO2 coating was deposited on 20MnNiMo steel via atmospheric plasma spraying. The corrosion behavior of the coating was investigated in both artificial seawater and a simulated environment with hydrogen sulfide and high pressure. Additionally, ion dissolution experiments were conducted to evaluate the coating’s bio-friendliness. In artificial seawater, the corrosion rate (based on the corrosion current) of the Al2O3-40TiO2 coating initially decreased before increasing. It was speculated that the blocking of corrosion products in the defect channels was helpful in delaying the progress of corrosion in the early stage. The coating had a corrosion current on the order of 10−6 A/cm2 in artificial seawater, suggesting good protection in conventional seawater environments. In the simulated environment, the corrosion rate (based on the weight loss) of the Al2O3-40TiO2 coating showed a continuously declining trend. It was deduced that, unlike corrosion products in artificial seawater, the corrosion products in the simulated environment (e.g., metal sulfide) might be more chemically stable, leading to a longer blocking effect. Therefore, a minimal corrosion rate of 0.0030 mm/a was obtained after the coating was immersed for 30 days. The amount of dissolved coated elements was negligible and there were only small amounts of dissolved non-coated elements such as Ni and Mo. The developed coating can be considered to be highly biofriendly if the non-coated area of the specimen is well sealed.

The effect of NaCl concentration on impact-sliding fretting corrosion behavior of Inconel 690TT heat transfer tubes

The effect of NaCl concentration on impact-sliding fretting corrosion behavior of Inconel 690TT heat transfer tubes

A Review: Characterization Of Aluminium-Metal Matrix Composite Reinforced with Zirconium Diboride

Composite materials with aluminium matrices are used in thermal management, defence, aerospace, automotive and aviation. As the prices of useful items decreased, their usefulness increased. Aluminium is reinforced with other metals, non-metals and ceramics to give it the required physical and mechanical properties such as high tensile strength, great hardness and corrosion resistance. Aluminium-metal matrix composites are known for their exceptional physical and mechanical properties and performance. This work also focuses on the fabrication and characterization of zirconium diboride reinforced aluminium-metal matrix composite. Zirconium diboride particles were used as reinforcement material to fabricate aluminium metal matrix composites by the stir casting method. The microstructure, hardness and tensile strength of aluminum-metal matrix composites and its corrosion behaviour were investigated. The results showed that the inclusion of zirconium diboride particles increased the hardness and tensile strength of aluminum-metal matrix composites. Field emission scanning electron microscopy and x-ray diffraction analysis are used to investigate the microstructural properties of aluminum-metal matrix composites reinforced with zirconium diboride particles. Field emission scanning electron microscopy images showed a uniform distribution of zirconium diboride particles in the aluminum-metal matrix composites matrix. X-ray diffraction analysis showed the formation of an intermetallic compound of aluminium and zirconium diboride. From the review that have been made, we can conclude that the inclusion of zirconium diboride particles increased the mechanical properties and corrosion of aluminium-metal matrix composites.

The effect of Al on the corrosion resistance of binary Mg-Al solid solutions: Combining in-situ electrochemistry with combinatorial thin films

The effect of varying Al concentrations on the electrochemical corrosion resistance of binary Mg-Al solid solutions thin films under alkaline immersion conditions was investigated via a combination of in-situ flow-cell, scanning vibrating electrode technique and microscopy analysis. These spatially resolving characterization techniques are employed along the Al concentration gradient of the combinatorically grown thin films enabling efficient screening of the Al concentration dependent electrochemical corrosion behaviour. The analysis revealed an increasing corrosion resistance with increasing Al concentration, as a consequence of Al induced hydroxide reinforcement. Specifically, the addition of >4 wt.% Al decreases the corrosion current density in the range of 70–90 % compared to pure Mg.

Corrosion behavior analysis of steel in simulated carbonated concrete pore solution based on 3D optical microscopy method

The main purpose of this study was to analyze the corrosion behavior of steel in simulated carbonated concrete pore solution (SCCPS) with the help of 3D optical microscopy method. This method was adopted to provide qualitative observation of surface with 3D information and quantitative results of defects for steel which was affected by various NaCl contents and inhibitors (inorganic inhibitor (NaNO2) and organic inhibitor (DEA(C4H11NO2)). As the NaCl contents changed during all corrosion periods, the mean pitting depths (Ra) and NaCl contents showed stronger linear relationships, and the slop values presented as the Ra added value of per wt% for different inhibitor systems were all detected to be closed to 3 μm/wt% in all linear regression models. This method provided a new angle to investigate and estimate the defect variation on steel surface, which denoted to better understand the corrosion behavior in SCCPS. Additionally, electrochemical impedance spectroscopy (EIS) and weight loss measurements were also used to verify the results of 3D optical microscopy analysis.

Corrosion behavior and antibacterial adhesion of superhydrophobic composite coatings on AZ31 magnesium alloys

Corrosion behavior and antibacterial adhesion of superhydrophobic composite coatings on AZ31 magnesium alloys

Corrosion Behavior of Pre-oxidized GH4169 Alloy with Solid NaCl Deposited in a Wet Oxygen Flow at 600 °C

Corrosion Behavior of Pre-oxidized GH4169 Alloy with Solid NaCl Deposited in a Wet Oxygen Flow at 600 °C

Comparison of microstructure, mechanical, and electrochemical performance of laser-deposited FeCrV15 alloy at varying powder feed rates

In the realm of surface modification, repair, and reinforcement of components exposed to challenging operational conditions, such as tillage tools, laser cladding stands out as an innovative manufacturing technique. Employing this additive manufacturing approach, a functionally graded material with outstanding strength and properties is incorporated to enhance the desired attributes of the base material. This comparative investigation scrutinized and assessed the microstructural characteristics, hardness, wear resistance, and corrosion behavior of high carbon ferrochrome FeCrV15 coatings fabricated at two distinct powder feed rates, namely 5 and 6 g/min, respectively. The analysis delved into how the resultant coatings' molten bead deposition, microstructural evolution, hardness, wear resistance, and corrosion resistance were influenced by the powder feed rate. Evaluation of hardness was conducted using a Vickers microhardness testing apparatus, while phase identification was accomplished utilizing an X-ray diffractometer. The morphologies of the microstructures were scrutinized employing optical microscopy and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS). Furthermore, the corrosion response of the deposits in a soil–water environment was probed utilizing an Autolab potentiostat. A comprehensive assessment of the coatings' sliding wear performance was undertaken using an Anton Paar Tribometer. The findings of the study reveal that an escalation in the powder feed rate engenders heightened grain refinement within the microstructure, yielding a defect-free sample and augmenting the wear performance (with a wear rate of 2.42 × 10–6 mm3/N/m for sample B, surpassing 2.39 × 10–5 mm3/N/m for sample A and outstripping 1.72 × 10–3 mm3/N/m for the steel substrate). Additionally, the corrosion resistance is enhanced (with a corrosion rate of 0.0032 mm/yr for sample B, surpassing 0.0036 mm/yr for sample A, which, in turn, exceeds 0.1168 mm/yr for the steel substrate) in the case of sample B.

High-temperature creep and corrosion behavior of 316LN stainless steel in oxygen-saturated sodium

The high-temperature performance and sodium corrosion of in-core components are the main problems of liquid sodium-cooled reactors, and low-carbon nitrogen-controlled 316 stainless steel (316LN) is the main research and development direction of the main materials for the core of sodium-cooled fast reactors. In this work, the creep behavior of 316LN in oxygen-saturated liquid sodium at high temperatures (650 ℃, 700 ℃ and 750 ℃) was tested and compared with the results of creep tests in air at the same conditions. It is found that the creep life in the sodium environment is reduced by 63.44%, 67.93% and 40.07%, respectively. The specimens in oxygen-saturated sodium exhibit reduction in ductility, selective dissolution as well as oxidative corrosion. The corrosion mechanism of 316LN under external loading in oxygen-saturated sodium is illustrated.

Revealing the coupling of multiple corrosion behaviors in the corrosion process of titanium-steel composites in marine environment

In this study, the corrosion behavior and corrosion mechanism of titanium-steel composite plate was studied through immersion tests in simulated marine solution. The result shows that the corrosion behavior of titanium-steel composite plate is coordinated by various corrosion behaviors in the near interface area and the far interface area. The corrosion behavior of carbon steel matrix in the far interface area of titanium-steel composite plate in simulated solution is the same as that of carbon steel, because it is far from the interface and is not accelerated by galvanic effect. The corrosion reactions started with localized corrosion induced by inclusions and the diffusion of aggressive ions, and then changed from localized to uniform corrosion. The carbon steel at the interface is accelerated by galvanic effect in the early stage, and the tiny defects at the interface can also be used as the basic point of corrosion initiation. In the later stage, the corrosion at the interface reached a certain level, and the corrosion at the interface turned into the joint action of galvanic corrosion and crevice corrosion. In the whole corrosion process, corrosion is more likely to occur due to stress concentration at the interface. Under the combined action of different corrosion behaviors, the corrosion rate at the interface of titanium-steel composite plate is faster than that at the far interface area.

Influence of Candida albicans-Streptococcus mutans cross-border interactions on the corrosion behaviour of Ti and Ti-Zr in artificial saliva

This study evaluated and compared the corrosion effects of Streptococcus mutans (S. mutans), Candida albicans (C. albicans), and their mixture on implant materials Ti and Ti-Zr. Corrosion tests were conducted in simulated artificial saliva. The results showed differences in biofilm structure, corrosion behavior, and mechanisms between single and mixed bacteria. The cross-kingdom interaction between S. mutans and C. albicans enhanced biofilm maturity and acidity, providing necessary conditions for pitting corrosion. C. albicans played a dominant role in the interaction between C. albicans and S. mutans. Furthermore, Ti-Zr exhibited higher corrosion resistance compared to Ti.